发明名称 RING FLUORINATION OF INACTIVATED AROMATIC COMPOUND
摘要 PROBLEM TO BE SOLVED: To provide a method for electrophilically fluorinating a substrate with an excellent electrophilically fluorinating agent. SOLUTION: A non-substituted aromatic compound or an aromatic compound having one or more electrophilic substituents is fluorinated by making it come into contact with a tri(halo or trifluoromethyl)substituted N-fluorotriazinium salt of the formula I, three A parts are independently CR and each R is independently a halogen or trifluoromethane, or two A parts are independently Z and Z is independently N or a quaternary nitrogen atom; Y<-> is a counter ion or a group of counter ions inactive against chemical attack by fluorine; and the cation of the salt is preferably 2,4,6-trichloro-1,3,5-triazinium) preferably in a nitromethane solvent.
申请公布号 JP2002255861(A) 申请公布日期 2002.09.11
申请号 JP20010326456 申请日期 2001.10.24
申请人 AIR PRODUCTS & CHEMICALS INC 发明人 BANKS RONALD ERIC;BESHEESH MOHAMED KHALIFA
分类号 C07B39/00;C07C17/12;C07C25/13;C07C41/22;C07C43/225;C07C201/12;C07C205/12;C07D251/24;C07D251/28;(IPC1-7):C07B39/00 主分类号 C07B39/00
代理机构 代理人
主权项
地址