Process for the preparation of polyisocyanates by reaction of carboxylic acids with isocyanates, products prepared by this process and their use in polyurethanes

摘要

Preparation of a polyisocyanate with acylurea groups involves reacting an isocyanate (I) with an aliphatic and/or aromatic carboxylic acid in the presence of a metal-salt catalyst at 20-220 degrees C. Preparation of a polyisocyanate with acylurea groups involves reacting an isocyanate of formula (I) with an aliphatic and/or aromatic carboxylic acid in the presence of a metal-salt catalyst at 20-220 degrees C. R-(NCO)n (I) R = n-valent linear or branched 4-30C (cyclo)aliphatic group or 6-24C aromatic group; and n = 1-4. Independent claims are included for the following: (1) Polyisocyanate with acylurea groups; and (2) A polyurethane coating composition containing a binder comprising polyisocyanate.