摘要 |
<p>A process for preparing a halogenated aliphatic-α,β-unsaturated-β-nucleophile-functionalized carboxylate ester having the formula: R1-C(-Nu)=CH-COOR8 by reacting a nucleophile with a halogenated aliphatic-α,β-unsaturated-β halocarboxylate ester having the formula: R1-CX1=CH-COOR8, wherein R1 is selected from the group consisting of straight chain and branched halogenated C¿1?-C12 aliphatic groups; Nu is a nucleophile moiety different from X?1; X1¿ is F, Cl or Br; and R8 is selected from the group consisting of straight chain and branched C¿1?-C6 alkyl groups. Halogenated aliphatic-α,β-unsaturated-β-nucleophile-functionalized carboxylate esters, halogenated aliphatic-α,β-unsaturated-β-halocarboxylate esters, and intermediate compounds and processes in the preparation thereof are also disclosed.</p> |