发明名称 |
METHOD FOR PRODUCING 2-ALKYL-2-ADAMANTYL(METH)ACRYLATES |
摘要 |
PROBLEM TO BE SOLVED: To provide a method with which 2-alkyl-2-adamantyl(meth)acrylates can be industrially efficiently produced by a simple process in a high yield. SOLUTION: This method for producing 2-alkyl-2-adamantyl(meth)acrylates represented by general formula 5 (R2 is hydrogen or a methyl group; R1 an alkyl group;) comprises reacting 2-adamantanones represented by general formula 1 with an organometallic compound represented by general formula 2: R1-M (2) [R1 is as described above; M is a metal atom which may contain a ligand or a group represented by general formula 3: -MgY (3) (Y is a halogen)] to give 2-alkyl-2-adamantanols represented by general formula 4 (R1 is as described above and the adamantine ring may contain a substituent group) and then reacting the 2-alkyl-2-adamantanols with a (meth)acrylic acid halide. |
申请公布号 |
JP2002193883(A) |
申请公布日期 |
2002.07.10 |
申请号 |
JP20000389631 |
申请日期 |
2000.12.21 |
申请人 |
DAICEL CHEM IND LTD |
发明人 |
KOBAYASHI KENJI;WAZAKI TAKAHIRO |
分类号 |
G03F7/039;C07C67/14;C07C69/54 |
主分类号 |
G03F7/039 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|