发明名称 PHOSPHINITO-OXAZOLINE AND METAL COMPLEX
摘要 PROBLEM TO BE SOLVED: To provide a new phosphorus-containing oxazoline compound, a metal complex containing the compound as a ligand and a method for producing a chiral organic compound by the asymmetric addition reaction to a multiple bond using the metal complex as a catalyst. SOLUTION: The objective compound is a chiral ligand of a complex of a metal of subgroups I and VIII, useful as a catalyst for the asymmetric addition reaction to a prochiral unsaturated organic compound and expressed by general formula [X1 is a secondary phosphino group; R3 is H, a 1-20C hydrocarbon group, a hetero-hydrocarbon group bonded through C atom and having 2-20 atoms and one or more hetero-atoms consisting of O, S or NR or ferrocenyl; R is H or a 1-4C alkyl; R4 groups are each a 1-20C hydrocarbon group or both R4 groups together form a 1-20C hydrocarbon group; and R01 and R02 are each independently H or a 1-20C hydrocarbon group].
申请公布号 JP2002187895(A) 申请公布日期 2002.07.05
申请号 JP20010289902 申请日期 2001.09.21
申请人 SOLVIAS AG 发明人 PFALTZ ANDREAS;BLANKENSTEIN JOERG L;MENGES FREDERIK
分类号 B01J31/24;C07B53/00;C07B61/00;C07C5/03;C07C15/18;C07C41/20;C07C43/205;C07C67/303;C07C69/612;C07C209/52;C07C211/27;C07C233/18;C07C233/69;C07D263/14;C07D263/16;C07F9/653;C07F15/00;C07F17/02;(IPC1-7):C07F9/653 主分类号 B01J31/24
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