| 摘要 |
The present invention relates to a method of homo- or co-polymerization of alpha -olefin by means of using a catalyst system which comprises the following components: 1) a solid complex titanium catalyst produced by means of a production method comprising the following steps: a) preparing a magnesium compound solution by dissolving a magnesium halide compound and a compound of Group IIIA of the Periodical Table in a solvent of mixture of cyclic ester, one or more types of alcohol, a phosphorus compound, and an organic silane; b) precipitating the solid particles by reacting said magnesium compound solution with a transitional metal compound, a silicon compound, a tin compound, or the mixture thereof; and c) reacting said precipitated solid particles with a titanium compound and electron donors; 2) an organometallic compound of metal of Group IIIA of the Periodical Table; and 3) external electron donors comprising three or more types of organo-silicon compounds, wherein the melt flow rates of the homopolymers obtained from polymerization by individually using said organo-silicon compounds under the same polymerization conditions are 5 or less, 5 SIMILAR 20, and 20 or higher, respectively. According to the present invention, it has an advantage of obtaining polymers of broad molecular weight distribution with high hydrogen reactivity and melt flow rates while maintaining high stereoregularity and yields for olefin homo- or co-polymers during homo- or co-polymerization of alpha -olefin having three or more carbon atoms. |
