Mixtures of water soluble reactive azo dyes, process to manufacture them and their use

摘要

Dye mixtures contain 2-acylamino-4-amino-azobenzene dye(s) (I) and 4-(phenyl- or phenylcarbamoylphenyl-azo)-5-hydroxy-1-phenylpyrazole dye(s), both of which contain a vinylsulfonyl (precursor) group, in a (I):(II) molar ratio of 75:25 to 25:75. Dye mixtures contain 2-acylamino-4-amino-azobenzene dye(s) of formula (I) and 4-(phenyl- or phenylcarbamoylphenyl-azo)-5-hydroxy-1-phenylpyrazole dye(s) of formula (II), both of which contain a vinylsulfonyl (precursor) group, in a (I):(II) molar ratio of 75:25 to 25:75; M = hydrogen (H) or an alkali metal; Y<1>, Y<2> = vinyl or ethyl with a substituent eliminated by alkali in the beta -position; R<1> = H, chlorine (Cl), 1-4 C alkyl, 1-4 C alkoxy, carboxyl or sulfo; R<2>, R<5> = H, 1-4 C alkyl or 1-4 C alkoxy; R<3>, R<6> = H, 1-4 C alkyl, 1-4 C alkoxy or sulfo; R = optionally substituted 1-6 C alkyl or amino; R<4> = H, Cl, 1-4 C alkyl, 1-4 C alkoxy or sulfo; R<7> = methyl or carboxy; R<8>, R<9> = H, 1-4 C alkyl, 1-4 C alkoxy or Cl; m = 0, 1 or 2; n = 0 or 1.