发明名称 |
ARYLBIS (PERFLUOROALKYLSULFONYL) METHANE, METAL SALT OF THE SAME, AND PROCESSES FOR PRODUCING THESE |
摘要 |
A process for highly efficiently producing various arylbis(perfluoroalkylsulfonyl)methanes which have a bulky aryl group or electron-attracting aryl group and which have conventionally been regarded as difficult to synthesize; a novel arylbis(perfluoroalkylsulfonyl)methane widely applicable as a catalyst for asymmetric synthesis, various functional materials, etc.; metal salts of these; and an excellent catalyst. An arylhalomethane is reacted with sodium trifluoromethanesulfinate. The arylmethyltrifluorocarbon yielded is reacted with t-BuLi, etc. The arylmethyltrifluorocarbon lithium salt obtained is reacted with trifluoromethanesulfonic anhydride. Thus, an arylbis(trifluoromethylsulfonyl)methane, e.g., pentafluorophenylbis(trifuryl)methane or {4-(pentafluorophenyl)-2,3,5,6-tetrafluorophenyl}bis(trifuryl)methane, is obtained in high yield.
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申请公布号 |
WO0248098(A1) |
申请公布日期 |
2002.06.20 |
申请号 |
WO2001JP10978 |
申请日期 |
2001.12.14 |
申请人 |
JAPAN SCIENCE AND TECHNOLOGY CORPORATION;ISHIHARA, KAZUAKI;YAMAMOTO, HISASHI |
发明人 |
ISHIHARA, KAZUAKI;YAMAMOTO, HISASHI |
分类号 |
B01J31/02;B01J31/12;C07C45/69;C07C67/08;C07C317/10;(IPC1-7):C07C317/10;C07C315/00;B01J31/22;C07C69/78;C07C47/445 |
主分类号 |
B01J31/02 |
代理机构 |
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地址 |
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