发明名称 Optimization of polycarbonate preparation by transesterification
摘要 Acidic impurities in dihydroxyaromatic compounds such as bisphenol A, as illustrated by sulfonic acids and mercaptocarboxylic acids, can have an adverse effect on the molecular weight of a polycarbonate prepared therefrom by transesterification. The same is true of acidic impurities in diaryl carbonates such as diphenyl carbonate, as illustrated by salicylic acid and ferric chloride. The reagents are analyzed for these impurities. Based on the analysis, the reagents are discarded or recycled, or a compensatory amount of alkali metal hydroxide is employed as a catalyst in the reaction.
申请公布号 US6403754(B1) 申请公布日期 2002.06.11
申请号 US20010770487 申请日期 2001.01.29
申请人 GENERAL ELECTRIC COMPANY 发明人 MCCLOSKEY PATRICK JOSEPH;SMIGELSKI, JR. PAUL MICHAEL;BURNELL TIMOTHY BRYDON;ORDONEZ JUAN RODRIQUES;FERNANDEZ IGNACIA VIC;HIDALGO-LLINAS GERARDO;PEEMANS RUDY FRANCOIS ALAIN J.;VENAMA EDWARD
分类号 C08G63/83;C08G64/30;(IPC1-7):C08G64/00 主分类号 C08G63/83
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