Oil soluble metal-containing compounds, compositions and methods

摘要

Radiation curable compositions for coatings, adhesives, inks, and molded articles are disclosed. The radiation curable compositions comprise (A) at least one polymerizable, ethylenically unsaturated compound of one of the following formulas:whereinM is one or more metal atoms of valence n, wherein n=y.w, wherein M is optionally more than one metal atom, with the proviso that the global equivalent metal valence is n=w.y;n is an integer of about 1-6;R is a residue of a compound having anhydride and/or carboxylic acid groups with initial equivalent carboxy equivalent functionality defined by the equation f=x+y+z, wherein f is an integer of about 2 to 30;R1 is a residue of a hydroxy-containing ethylenically unsaturated compound;R2 is H or a residue of a hydroxy containing ethylenically unsaturated compound different from R1;R3 is a residue of a hydroxy-containing ethylenically unsaturated compound;w is the number of moieties having residue R required for valence n;x is an integer of about 1 to f-1;y is an integer of about 1 to 2 (the number of intramolecular carboxylates bonded to M);z is an integer of about 0 to f-2;Y is H or R3; and(B) at least one copolymerizable ethylenically unsaturated monomer or oligomer.