发明名称 |
Process for making poly (urethane-urea)/addition polymer composite particles |
摘要 |
A process for making poly(urethane-urea)/addition polymer composite particles which avoids the need to use a highly viscous solution of a prepolymer for the poly(urethane-urea). The process comprises dissolving diol and di-isocyanate in addition polymerisable monomers and allowing them to co-react but for only long enough to form a precursor for the prepolymer which is of a lower molecular weight than the prepolymer so that the precursor forms a solution of much lower viscosity. This lower viscosity solution is then dispersed in water to give droplets in which the co-reaction continues and completes the formation of the prepolymer whilst water diffuses into the droplets and causes chain extension to create the poly(urethane-urea) particles. The addition polymerisable monomers in the dispersed droplets spontaneously diffuse into the poly(urethane-urea) particles where they are subjected to a conventional free radical addition polymerisation process whereupon composite the poly(urethane-urea)/addition polymer particles are formed. The composite particles can be obtained as stable aqueous dispersions optionally containing less than 3 wt % organic solvent and over 40 wt % of the composite particles.
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申请公布号 |
US2002058751(A1) |
申请公布日期 |
2002.05.16 |
申请号 |
US20010907646 |
申请日期 |
2001.07.19 |
申请人 |
IMPERIAL CHEMICAL INDUSTRIES PLC. |
发明人 |
WILLIAMS NEAL ST. JOHN |
分类号 |
C08F283/00;C08G18/08;C08G18/66;C09D175/06;(IPC1-7):C08K3/00;C08K3/20 |
主分类号 |
C08F283/00 |
代理机构 |
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主权项 |
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