摘要 |
PURPOSE: Provided is a method for producing a polyvinyl ester resin emulsion which has high viscosity and has good water resistant adhesiveness, heat-resistant adhesiveness, hot water-resistant adhesiveness and storage stability, especially high-temperature storage stability, and which has good film-forming ability and is readily formed into transparent films. CONSTITUTION: The method for producing a polyvinyl ester resin emulsion, comprises polymerizing a vinyl ester monomer by emulsion polymerization in the presence of a polyvinyl alcohol as a protective colloid and in the presence of a water-insoluble, hydroxyl group-containing compound. The polyvinyl alcohol contains from 0.5 mol% to 20 mol% of ethylene units. The polyvinyl ester resin emulsion is an emulsion of a copolymer of a vinyl ester monomer and ethylene. The water-insoluble, hydroxyl group-containing compound is a water-insoluble ester alcohol compound.
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