| 摘要 |
A process is described for the polycondensation of organic silicon compounds at from pH 6 to 8 in the presence of a lipase which is, where appropriate, immobilized on a carrier composed of polymer materials. Suitable organic silicon compounds capable of polycondensation are (RO)(R1O)(R2O)(R3O)Si, (RO)(R1O)(R2O)SiR3, (RO)(R1O)Si (R2)(R3) and (RO) SiR1R2R3, where R, R1, R2 and R3 are independently of one another C1- to C10-alkyl, C3- to C10-cycloalkyl, C4- to C20-alkylcycloalkyl, aryl, C6- to C16-alkylaryl, the alkyl groups being linear or branched. It is advantageous and possible to obtain the lipase on a large scale relatively simply by fermentation processes. Preference is given to employing lipases from Pseudomonas species. |
