发明名称 METHOD OF PRODUCING ALICYCLIC (METH)ALLYL ESTER MONOMER, ALICYCLIC (METH)ALLYL ESTER, COMPOSITION FOR PLASTIC LENS INCLUDING THE SAME AND PLASTIC LENS PRODUCED BY CURING THE PLASTIC LENS COMPOSITION
摘要 PROBLEM TO BE SOLVED: To provide an alicyclic (meth)allyl ester for plastic lens that can be simply produced with high resistance to storage for a long period of time and provide a method for producing the same. SOLUTION: The objective alicyclic (meth)allyl ester monomer, for example, diallyl 1,4-cyclohexanedicarboxylate, is produced by allowing an alkyl ester of a polybasic acid bearing an alicyclic structure to react with allyl alcohol or methallyl alcohol in the presence of a transesterification reaction catalyst (at least one selected from a combination of an alkali metal salt of an organic and/or inorganic acid with an alkaline earth metal hydroxide and/or oxide, an organometallic complex, an organometallic compound, a tertiary amine, an alkali metal and/or alkaline earth metal carbonate salt and an alkali metal alkylalkoxides). The resultant monomer is allowed to react with polyhydric alcohol in the presence of a catalyst to produce an alicyclic (meth)allyl ester bearing a terminal structure of general formula 1 and the recurring units of general formula 2. This invention further relates to a composition for plastic lens containing the alicyclic (meth)allyl ester monomer and to plastic lens therefrom.
申请公布号 JP2002069035(A) 申请公布日期 2002.03.08
申请号 JP20010116797 申请日期 2001.04.16
申请人 SHOWA DENKO KK 发明人 OGA KAZUHIKO;TAJIMA TSUNEO;UCHIDA HIROSHI
分类号 G02B1/04;C07B61/00;C07C67/03;C07C69/75;C08F218/00;G02B3/00;(IPC1-7):C07C67/03 主分类号 G02B1/04
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