摘要 |
New sulfur-vulcanizable, silica-reinforced tire rubber compositions and tires and tire parts, vulcanized and unvulcanized, made employing them are made with coupling agent compositions comprising a sulfur-containing norbornanyl silicon compound of the structure [Sy-R]n-SiX4-n wherein each X is chosen from monovalent hydrocarbon groups or hydrolyzable groups; y is 1 to 5 when y is 1 the compound is an episulfide, and when y is 2 to 5 the sulfur atoms form a polysulfide wherein each sulfur atom is bonded to another sulfur atom and the terminal valences of the polysulfide are bonded to vicinal carbon atoms; n is 1, 2 or 3; R is a polyvalent polycycloaliphatic hydrocarbon radical. Tires made with these compositions exhibit a desirable combination of properties, including reduced rolling resistance and road noise and maintained or improved modulus, wet traction and abrasion resistance.
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