发明名称 |
Method for producing high purity vanadium electrolytic solution |
摘要 |
<p>A method for producing an electrolytic solution containing vanadium as positive and negative electrode active material, the electrolytic solutions being suitable for a redox battery which comprises: the steps of (1) a vanadium compound is dissolved in a solvent under an alkaline or neutral condition, a polyvanadate compound is precipitated and isolated by thermal polymerization of vanadium ions under an acidic condition; (2) a part of the polyvanadate compound is baked in an inert or oxidizing gas atmosphere so as to remove ammonium ions; (3) a trivalent vanadium compound is formed by treating another part of the polyvanadate compound under a reductive atmosphere; (4) a trivalent vanadium electrolytic solution is formed by dissolving the trivalent vanadium compound in an acid solution; and (5) vanadium pentoxide and a part of the trivalent vanadium compound are reacted by mixing so that mixed electrolytic solutions of V<4><+> and V<3><+> are formed. According to the present invention, a high purity vanadium electrolytic solution can be economically produced even from vanadium pentoxide and ammonium metavanadate raw materials containing large quantities of impurities.</p> |
申请公布号 |
EP0713257(B1) |
申请公布日期 |
2002.02.13 |
申请号 |
EP19950117964 |
申请日期 |
1995.11.14 |
申请人 |
KASHIMA-KITA ELECTRIC POWER CORPORATION |
发明人 |
NAKAJIMA, MASATO;AKAHOSHI, TOSHIAKI;SAWAHATA, MASATOSHI;NOMURA, YUTAKA;SATO, KANJI |
分类号 |
C01G31/00;H01M8/06;H01M8/18;(IPC1-7):H01M8/18 |
主分类号 |
C01G31/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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