发明名称 Process for the preparation of enantiomerically pure pyrethroid insecticides
摘要 A process for producing compounds of formula (VIIa) and (VIIb) wherein X is a leaving group; Y and Y<1 >are idependently Cl or Br; and Z is Cl, Br or a haloalkyl group which process comprises a) reacting a compound of formula (VII) wherein X, Y, Y<1 >and Z are as defined for compounds (VIIa) and (VIIb) with a substantially optically pure chiral amine in a solvent to form a diastereoisomeric salt; b) separating the diastereomeric salt of each enantiomer; c) converting the diastereomeric salt of each anantiomer separately to compounds of formulae (VIIa) and (VIIb) respectively by acid or base hydrolysis, the use of the compounds in making pyrethroid insecticides and novel intermediates.
申请公布号 AU7082901(A) 申请公布日期 2002.01.30
申请号 AU20010070829 申请日期 2001.07.16
申请人 SYNGENTA LIMITED 发明人 STEPHEN MARTIN BROWN;BRIAN DAVID GOTT
分类号 C07C51/487;A01N53/06;C07C51/09;C07C51/377;C07C51/41;C07C51/60;C07C55/32;C07C55/40;C07C61/15;C07C61/40;C07C67/14;C07C69/63;C07C69/74;C07C69/747 主分类号 C07C51/487
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