METHODS FOR WASTE TREATMENT

摘要

PCT No. PCT/AU93/00489 Sec. 371 Date May 1, 1995 Sec. 102(e) Date May 1, 1995 PCT Filed Sep. 21, 1993 PCT Pub. No. WO94/06575 PCT Pub. Date Mar. 31, 1995Methods for waste treatment and compositions of stabilized waste elements are provided, typically for the disposal of arsenical wastes. Arsenic trioxide waste produced as a by-product of metal extraction is slurried in water for from 6 to 24 hours with finely divided quicklime to produce nonvolatile calcium arsenate (III). An excess of CaO stoichiometry with As is used to consume secondary waste species such as sulphate, silicate and iron oxides. The precipitated arsenate is oven dried at 120 DEG C. and then calcined in air between 15 minutes to several hours at 1000 DEG C. to 500 DEG C. respectively to oxidize arsenate (III) to arsenate (V) as Ca5(AsO4)3(OH) (an apatite) as the major arsenic immobilization phase, with minor arsenic incorporated in Ca3(AsO4)2. Calcium sulphate anhydrate (sulphate immobilization) and calcium iron oxide (iron immobilization) are also produced. Tertiary immobilization is achieved milling or fracturing and incorporating the apatite an encapsulant consisting of ordinary portland cement and flyash. After curing for one month in steel drums in a water saturated atmosphere, the waste form is ready to be transported either to a repository or to used as landfill. Further security may be achieved at the back end of the process by lining the repository with ferric clays that will strongly absorb and adsorb heavy metal species which may escape.