摘要 |
The heat-sensitive water-soluble copolymer is obtained from a composition of water-soluble monomers comprising, for 100 molar parts (pp): from 10 to 69 pp of at least one compound (I) and/or (II); from 30 to 75 pp of at least one ethylenically unsaturated sulphonic acid; from 0 to 50 pp of at least one compound (III) and/or (IV); from 0 to 30 pp of at least one compound (V) and/or (VI); from 0 to 30 pp of at least one other monomer such as (VII) and/or (VIII) and/or (IX) and/or acrylonitrile and/or allyl alcohol and/or vinylpyridine and/or an unsaturated monomer which is a carboxylic acid or an anhydride of a carboxylic acid and/or a silane monomer and/or a phosphate-function monomer and/or a phosphonated monomer and/or a monomer having N-vinyl groups; and from 0.001 to 50 pp of at least one hydrophobic monomer. R<1>, R<3>, R<7>, R<8>, R<11>, R<16>, R<17>, R<24>, R<28>, R<31>=H, -CH3; R<2>, R<6>=-CH2-CH2 which may bear at least one OH or C3-C4 alkylene radical bearing at least one OH radical; and R<9>, R<10>, R<14>, R<15>, R<18>, R<22>=C2-C4 alkylene which may bear at least one OH radical, n, o, p, r, t, u=from 1 to 70; q, s=from 1 to 40 ;R<4>, R<5>, R<12>, R<13>, R<20>, R<21>=H, C2-C4 alkyl; Y<1>, Y<2>, Y<3>=single bond, C1-C4 alkylene; R<19>, R<23>=C2-C40 alkyl radical, C6-C60 aralkyl radical or aryl radical, A<1>, A<2>=O, NH; B<1>, B<3>=-CH2CH2-, -CH2CH2CH2-, -CH2CHOHCH2</s |