| 摘要 |
<p>A method of carrying out a reaction comprising the steps of: mixing at least one organic reaction component with at least one fluorous reaction component having the formula: X1Sn(R)n[Rs(Rf)]3-n, X1X2Sn[Rs(Rf)]¿2? or 0=Sn[Rs(Rf)]2 wherein n is 1 or 2, R is a C1-C6 alkyl group, X?1 and X2¿ are independently, the same or different, H, F, C1, Br, I, N¿3?, OR?1, OOR1, SR1, SeR1¿, CN, NC, NR1R2, an aryl group, a heteroaryl group, an alkyl group of 1 to 20 carbons, an alkenyl group, an alkynyl group, -C(O)R3, M((Rs')(Rf'))¿3?, OM((Rs')(Rf'))3 or OOM((Rs')Rf'))3, wherein M is Si, Ge, or Sn, and wherein R?1 and R2¿ are each independently the same or different H, an alkyl group, -SO¿2R?3 or -C(O)R3, wherein R3 is an alkyl group or an aryl group, and wherein Rs and Rs' are each independently the same or different a spacer group, and wherein Rf and Rf' are each independently the same or different a fluorous group; carrying out a reaction to produce an organic product; and after producing the organic product, separating any excess of the fluorous reaction component and any fluorous byproduct of the fluorous reaction component using a fluorous separation technique. Several compounds have the formula: X1Sn(R)n[Rs(Rf)]3-n, X1X2Sn[Rs(Rf)]¿2? or O-Sn[Rs(Rf)]2.</p> |
