发明名称 PLATINUM-MEDIATED SYNTHETIC PROCESS FOR Δ4-1,2,4-OXADIAZOLINES
摘要 <p>Δ4-1,2,4-oxadiazolines, of the general formula (I) (R1)=H; R, R2 or R3= alkyl or aryl), are prepared by the [2+3] cycloaddition reaction, in mild conditions, between organonitrile ligands (NCR), activated by coordination to platinum centres, and nitrones ON(R?3)=C(R1)(R2¿), giving complexes with Δ4-1,2,4-oxadiazolines which are liberated from the binding metal centres (in high yields) upon displacement with pyridine or an organophosphine.</p>
申请公布号 WO2001098283(A1) 申请公布日期 2001.12.27
申请号 PT2001000011 申请日期 2001.06.21
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