发明名称 Method for producing jasmonate derivatives and intermediates thereof
摘要 The present invention provides a method for efficiently producing a 2-alkyl-2-cyclopentenone as well as a method for producing a jasmonate derivative by using the same. That is, in the present invention, the compound (2) is obtained by reacting an amine and a hydrogen halide with the compound (1) at a specific ratio to carry out isomerization reaction or by reacting a catalyst comprising an amine and a hydrogen halide with the compound (3) to carry out dehydration-isomerization reaction. Further, this compound (2) is reacted with a malonic acid diester and then reacted with water to obtain a jasmonate derivative (5): wherein each of R1 and R2 represents H, a C1-8 alkyl group or the like, and R3 represents a C1-3 alkyl group.
申请公布号 US2001049455(A1) 申请公布日期 2001.12.06
申请号 US20010804227 申请日期 2001.03.13
申请人 KAO CORPORATION 发明人 ASADA TAKAHIRO;ATAKA YOSHIHARU;KOSHINO JUNJI
分类号 C07C45/66;C07C45/67;C07C67/343;(IPC1-7):C07C45/67 主分类号 C07C45/66
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