Method and apparatus for automatic analysis

摘要

A method for estimating the concentration of a reduced (or oxidised) form of a redox species in a liquid comprises contacting an area of a first electrode (2) with a sample (5) of the liquid, contacting the sample (5) with a second electrode (2) spaced apart from the first (2), applying a potential between the electrodes while the electrodes are sufficiently closely spaced that reaction products formed at each electrode diffuse to the other electrode while the potential is applied, measuring or estimating a value indicative of the change in current as a function of time and a value indicative of the steady state current, and determining from said volume, said current as a function of time, and said steady state current the concentration of reduced (or oxidised) form of the species in the liquid sample.