发明名称 |
VERFAHREN ZUR HERSTELLUNG VON UNGESÄTTIGTEN KETONEN |
摘要 |
<p>Unsaturated ketones, comprising optionally substituted but-3-enyl and/or buta-2.3-dienyl methyl ketones, are prepared by: (a) reacting allyl alcohols and/or propargyl alcohols with isopropenyl ethers, with formation of ketals as by-product; (b) preparing isopropenyl ethers by catalytic gas phase reaction of ketals with propyne and/or allene; and (c) feeding the ketal from stage (a) into stage (b). The but-3-enyl methyl ketones of formula (Ia) and but-2,3-dienyl methyl ketones of formula (Ib) formed, allyl alcohols of formula (IIa) and/or propargyl alcohols of formula (IIb) and isopropenyl ethers (III) used as starting materials are ketals (IV). R1, R2, R3, R4, R5 = H or (cyclo)alkyl, (cyclo)alkenyl or ar(alk)yl (optionally containing O); or R1R2 = 5-6-membered ring; and R6 = 1-4C alkyl. (III) are prepared by the gas phase reaction of (IV) and propyne or allene at elevated temperature in the presence of a heterogeneous catalyst containing Zn or Cd plus Si and O.</p> |
申请公布号 |
AT208363(T) |
申请公布日期 |
2001.11.15 |
申请号 |
AT19980116052T |
申请日期 |
1998.08.26 |
申请人 |
BASF AKTIENGESELLSCHAFT |
发明人 |
TELES, JOAQUIM HENRIQUE, DR.;RIEBER, NORBERT, DR.;BREUER, KLAUS, DR.;DEMUTH, DIRK, DR.;HIBST, HARTMUT, PROF. DR.;KAESHAMMER, STEFAN, DR.;ETZRODT, HEINZ, DR.;KAISER, WULF, DR. |
分类号 |
B01J23/06;C07B61/00;C07C45/51;C07C49/203;(IPC1-7):C07C45/51;C07C41/28;C07C41/08 |
主分类号 |
B01J23/06 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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