发明名称 |
HIGH ACTIVITY CATALYST PREPARED WITH ALKOXYSILANES |
摘要 |
An ethylene-alpha-olefin copolymerization catalyst is prepared by impregnating a silica calcined at elevated temperature sequentially with an organomagnesium compound such as dialkylmagnesium compound, a silane compound which is free of hydroxyl groups, such as tetraethyl orthosilicate. A transition metal component such as titanium tetrachloride is then incorporated into the support. Unexpectedly, the calcination temperature of the silica used to prepare the catalyst precursors has a strong influence on polymer product properties. By increasing the calcination temperature of the silica from 600° to 700° C. or higher temperatures, a catalyst precursor when activated produced ethylene/1-hexene copolymers with narrower molecular weight distributions (MWD) as manifested by a decrease of resin MFR values of ~3-4 units. Activation of this catalyst precursor with a trialkylaluminum compound results in a catalyst system which is effective for the production of ethylene copolymers. |
申请公布号 |
EP1017493(A4) |
申请公布日期 |
2001.11.07 |
申请号 |
EP19980934360 |
申请日期 |
1998.07.09 |
申请人 |
EXXONMOBIL OIL CORPORATION |
发明人 |
MINK, ROBERT, IVAN;NOWLIN, THOMAS, EDWARD |
分类号 |
C08F4/658;B01J21/08;B01J31/02;B01J31/12;B01J31/14;C08F4/02;C08F4/58;C08F4/64;C08F10/00;C08F10/02;C08F210/16 |
主分类号 |
C08F4/658 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|