发明名称 2-(METH)ACRYLOYLOXYMETHYL-2-METHYLBICYCLO[2.2.1]HEPTANE, METHOD OF MANUFACTURE, METHOD OF PURIFICATION OF RAW MATERIAL ALCOHOL, METHOD OF MANUFACTURE RAW MATERIAL ALDEHYDE AND (CO)POLYMER OF THE SAME
摘要 PROBLEM TO BE SOLVED: To provide a 2-(meth)acryloyloxymethyl-2-methylbicyclo[2.2.1]heptane (co)polymer having high heat resistance, the monomer and a method of producing the monomer efficiently, and to provide a method of purifying the raw material alcohol to obtain the monomer with high purity and a method of producing the raw material aldehyde efficiently. SOLUTION: The 2-(meth)acryloyloxymethyl-2-methylbicyclo[2.2.1]heptane consisting of the exo and endo isomers in a 75:25-100:0 mass ratio is polymerized. The 2-(meth)acryloyloxymethyl-2-methylbicyclo[2.2.1]heptane consisting of the exo and endo isomers in the 75:25-100:0 mass ratio is manufactured by esterifying 2-hydroxymethyl-2methylbicyclo[2.2.1]heptane obtained by reduction of 2-formyl methylbicyclo[2.2.1]-5-heptene, with a (meth)acrylic acid derivative.
申请公布号 JP2001310910(A) 申请公布日期 2001.11.06
申请号 JP20010022228 申请日期 2001.01.30
申请人 MITSUBISHI RAYON CO LTD 发明人 DOI JUNICHI;MATSUMOTO SATOSHI;KAMON YOSHIHIRO;SONOBE HIROSHI;OKIMOTO YUKINORI
分类号 C07C29/86;C07C35/29;C07C45/69;C07C49/553;C07C67/03;C07C67/08;C07C69/653;C08F20/18;(IPC1-7):C08F20/18 主分类号 C07C29/86
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