发明名称 |
Ruthenium-phosphine complex and method for producing the same |
摘要 |
Disclosed is a ruthenium-phosphine complex usable as the catalyst giving a high enantiomer excess in an asymmetric reaction and a method for producing the complex. The ruthenium-phosphine complex is represented by formula (1):wherein R2 represents hydrogen, alkyl, cycloalkyl or benzyl and L represents a diphosphine ligand represented by formula (2):wherein R1 represents an optionally substituted phenyl group and X represents a halogen atom. The method for preparing a ruthenium-phosphine complex represented by formula (1) is characterized in that a ruthenium complex represented by the formula [RuX(arene)(L)]X and an ammonium salt represented by the formula R22NH.HX are reacted with each other.
|
申请公布号 |
US6313317(B1) |
申请公布日期 |
2001.11.06 |
申请号 |
US19990273260 |
申请日期 |
1999.03.22 |
申请人 |
TAKASAGO INTERNATIONAL CORPORATION |
发明人 |
SAYO NOBORU;SAITO TAKAO;YOKOZAWA TOHRU |
分类号 |
B01J31/24;C07B53/00;C07B61/00;C07C29/136;C07C31/20;C07C67/31;C07C67/333;C07C69/716;C07F15/00;(IPC1-7):C07F9/30;C07D317/50 |
主分类号 |
B01J31/24 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|