发明名称 Ruthenium-phosphine complex and method for producing the same
摘要 Disclosed is a ruthenium-phosphine complex usable as the catalyst giving a high enantiomer excess in an asymmetric reaction and a method for producing the complex. The ruthenium-phosphine complex is represented by formula (1):wherein R2 represents hydrogen, alkyl, cycloalkyl or benzyl and L represents a diphosphine ligand represented by formula (2):wherein R1 represents an optionally substituted phenyl group and X represents a halogen atom. The method for preparing a ruthenium-phosphine complex represented by formula (1) is characterized in that a ruthenium complex represented by the formula [RuX(arene)(L)]X and an ammonium salt represented by the formula R22NH.HX are reacted with each other.
申请公布号 US6313317(B1) 申请公布日期 2001.11.06
申请号 US19990273260 申请日期 1999.03.22
申请人 TAKASAGO INTERNATIONAL CORPORATION 发明人 SAYO NOBORU;SAITO TAKAO;YOKOZAWA TOHRU
分类号 B01J31/24;C07B53/00;C07B61/00;C07C29/136;C07C31/20;C07C67/31;C07C67/333;C07C69/716;C07F15/00;(IPC1-7):C07F9/30;C07D317/50 主分类号 B01J31/24
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