发明名称 OPTICALLY ACTIVE OXAZOLINE COMPOUND AND METHOD FOR PRODUCING OPTICALLY ACTIVE ALLYL ALCOHOL DERIVATIVE BY USING THE COMPOUND
摘要 PROBLEM TO BE SOLVED: To obtain a new optically active trisoxazoline compound capable of providing a copper complex having the compound as a ligand and extremely useful as a catalyst for an asymmetric allyl oxidation reaction. SOLUTION: This optically active trisoxazoline compound is represented by formula (1) [wherein, R is a 1-6C alkyl group, a phenyl group or a benzyl group; (*) represents an asymmetric carbon, and the absolute configuration of the carbon means R or S]. The method for producing an optically active allyl alcohol derivative is characterized in that a cyclic olefin is reacted with a peracid ester in the presence of the copper complex having the optically active trisoxazoline compound of formula (1) as the ligand.
申请公布号 JP2001294580(A) 申请公布日期 2001.10.23
申请号 JP20000112925 申请日期 2000.04.14
申请人 NISSAN CHEM IND LTD 发明人 KATSUKI TSUTOMU
分类号 C07D263/10;B01J31/22;C07B61/00;C07C67/297;C07C69/02;C07C69/78;C07D263/14 主分类号 C07D263/10
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