发明名称 METHOD OF PREPARING BIMETALLIC RUTHENIUM/TIN CATALYST, THUS PREPARED BIMETALLIC CATALYST, AND METHOD OF PREPARING ALDEHYDES AND THEIR DERIVATIVES
摘要 organic synthesis catalysts. SUBSTANCE: catalyst contains carrier and metal phase including partially intermetallic compound being at least partly in the form of Ru3Sn7, covering at least part of indicated carrier. Catalyst is prepared by depositing, onto carrier, ruthenium/tin complex, wherein oxidation state of ruthenium is equal to 4 and its coordination number to 6, said complex being depicted by general formula [Ru(SnX3)6-nXn]4-, wherein X denotes halogen atom (preferably chlorine or bromine), n is number between 0 and 2 (preferably 1), and cation A is hydrogen, after which complex is subjected to reduction. EFFECT: enabled formation of homogenous catalyst under industrial-scale conditions. 31 cl, 3 ex
申请公布号 RU2174872(C2) 申请公布日期 2001.10.20
申请号 RU19980110819 申请日期 1996.11.08
申请人 RODIA SHIMI 发明人 ROLAN ZHAKO
分类号 B01J23/62;B01J37/16;C07B61/00;C07C45/41;C07C47/16;(IPC1-7):B01J23/62 主分类号 B01J23/62
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