Polymer/support solid phase reactants, useful for a range of organic reactions and purification processes comprise funtionalized polymer particles in the pores of a porous support

摘要

Polymer/support solid phase reactants (I) comprise a fine particulate polymer of bonded particles having a diameter of 0.001-50 microns to which organic reactants are bound in the pores of a porous support having pore diameters of 0.1-2000 microns. Independent claims are included for: (i) a process for the preparation of the polymer/support solid phase reactants (I) by infiltrating a cross-linked polymer into the support material and functionalizing the polymer by post-treatment with further monomers whereby the polymer optionally contains anchor groups; (ii) a housing for the uptake of polymer/support solid phase reactants (I) that is permeable and pressure sealed and is installed either individually or connected together for the synthesis of organic products; and (iii) a device for the use of the polymer/support solid phase reactants (I) comprising a storage vessel (1), a pump (2) and a pipe (12) having a stop cock (3) and a check valve (4) connected to the upper side of the porous polymer/support solid phase reactant (5) and having at its lower side a dosing valve (6) and outlet for products (7) with a recycle loop comprising a stopcock (8), recycle pump (10) and check valve (11) to the upper side of the solid phase reactant (5).