发明名称 Hydrogen reduction of sulfonyl chlorides to thiols
摘要 This invention relates to a process for the production of an aryl thiol, which comprises hydrogenating an aryl sulfonyl chloride in a solvent in the presence of a palladium catalyst and a base whose conjugate acid has a pKa of about 2 or greater, wherein the base is selected from the group consisting of ionic bases soluble in water and tertiary amines soluble in the solvent, the tertiary amines not having a methyl group attached to the amine nitrogen.
申请公布号 AU3869901(A) 申请公布日期 2001.09.17
申请号 AU20010038699 申请日期 2001.02.26
申请人 E.I. DU PONT DE NEMOURS AND COMPANY 发明人 STEPHEN E. JACOBSON
分类号 C07B61/00;C07C319/02;C07C321/26 主分类号 C07B61/00
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