发明名称 METHOD OF PREPARING CARBAMIDOFORMALDEHYDE RESINS
摘要 manufacture of heat-insulating glass wool minerals in wood-working industry. SUBSTANCE: synthesis of resins by initial condensation in medium with variable acidity of carbamide with formaldehyde in the presence of catalyst which is hexamethylene tetramine production waste comprising, wt %: hexamethylene tetramine, 50-60; formate-ion, 7-15; formaldehyde, 0.15-0.5; and water, the balance up to 100. Amount of catalyst is 0.07-0.13 mole per mole of carbamide in terms of hexamethylene tetramine, hexamethylene tetramine is added directly after carbamide, and formaldehyde is then added in amount of 2.2-2.4 moles per 1 mole of carbamide. Product is then neutralized with alkali to pH of 8.0-9.0, cooled to 60-70 C, concentrated under vacuum, additional amount of 0.293-0.341 of initial amount of carbamide, and resins are stabilized with aqueous solutions of ammonia or alkali. As obvious from invention, resins are stable during storage, have lower content of formaldehyde and are completely miscible with water. EFFECT: more efficient preparation method. 6 cl, 5 ex, 1 tbl
申请公布号 RU2169739(C1) 申请公布日期 2001.06.27
申请号 RU20000125587 申请日期 2000.10.10
申请人 OTKRYTOE AKTSIONERNOE OBSHCHESTVO "METAFRAKS" 发明人 KIRICHENKO JU.D.;KORENOVSKAJA L.N.;BIBAKOVA T.A.;DAUT V.A.;OZHEGOV A.I.
分类号 C08G12/12;C08G12/40;(IPC1-7):C08G12/12 主分类号 C08G12/12
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