发明名称 |
Methods for the preparation of tris-aryl-o-hydroxyphenyl-s-triazines |
摘要 |
A process for preparing 2-(2,4-dihydroxyphenyl)-4.6-diaryl-s-triazines in three steps starting with cyanuric chloride is described. Step 1 involves the nucleophilic (basic) displacement of one chlorine atom with a phenolic moiety. Step 2 involves a Friedel-Crafts reaction using a Lewis acid catalyst (preferably aluminum chloride) to replace the remaining two chlorine atoms with aryl groups such as xylyl. Finally, step 3 involves replacing the phenolic moiety with resorcinol using either a Lewis acid or protic acid catalyst or combinations thereof. Some additional processes only peripherally related to the three-step process outlined above are also described for the preparation of various s-triazine compounds. The s-triazines prepared are useful as UV absorbers for the stabilization of organic substrates against the adverse effects of actinic light.
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申请公布号 |
US6242598(B1) |
申请公布日期 |
2001.06.05 |
申请号 |
US20000532222 |
申请日期 |
2000.03.22 |
申请人 |
CIBA SPECIALTY CHEMICALS CORPORATION |
发明人 |
STEVENSON TYLER ARTHUR;ACKERMAN MICHAEL;HAYOZ PASCAL;MEUWLY ROGER;OSWALD JOHN FRANCIS;SCHREGENBERGER CHRISTIAN |
分类号 |
C07D251/24;(IPC1-7):C07D251/22;C07D251/28 |
主分类号 |
C07D251/24 |
代理机构 |
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主权项 |
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