发明名称 |
PILLARED SILICA AND METAL OXIDE CATALYST AND PREPARATION METHOD OF -CAPROLACTAM THEREOF |
摘要 |
PURPOSE: Disclosed are a porous catalyst composed of pillard silica and metal oxide and a preparation method of ε-caprolactam from cyclohexanone oxime. CONSTITUTION: The porous catalyst is mainly composed of a pillard silica and a metal oxide. The sodium ion (Na+) on pillard silica is substituted with hydrogen ion (H+) of inorganic acid solution and a spacing width of pillard silica expands to 20 - 30 Å by using a long chained amine compound. And then metal oxide compounds are added in the spacing interval of the pillared silica. The added content of metal oxide is optimally 2 - 10 wt% and the surface area is 100 - 300 m2/g. The pillared silica is precipitated from kanemite, kenyaite, magadite, illite, octosilicate and Ta2O5, Nb2O5, TiO2 or SiO2 are used as metal oxides. |
申请公布号 |
KR20010028430(A) |
申请公布日期 |
2001.04.06 |
申请号 |
KR19990040680 |
申请日期 |
1999.09.21 |
申请人 |
KOREA INSTITUTE OF CONSTRUCTION TECHNOLOGY |
发明人 |
EO, YONG SEON;KIM, MYEONG HUN;KIM, SEON JIN;KIM, YEONG HUI |
分类号 |
B01J23/20;B01J29/04;B01J35/10;C07B61/00;C07D201/04;C07D223/10 |
主分类号 |
B01J23/20 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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