| 摘要 |
<p>A process for the production of n-butyl acrylate (BuAcA) including the steps of esterifying acrylic acid (HAcA) with n-butanol (n-BuOH) in a reaction zone, obtaining a condensate from the overhead vapors from the reaction zone which separates into organic and aqueous phases, feeding the organic phase comprising a major of BuAcA and minor portions of BuOH, water and light ends impurities to a finishing fractionation zone from which is obtained a side stream of a finished high purity BuAcA and an overhead condensate comprising BuAcA, BuOH, water and light ends, recycling most of the overhead condensate from the finishing zone to the reaction zone, feeding the remainder of such condensate to a purge recovery zone, obtaining an overhead condensate from the purge recovery zone which separates into organic and aqueous phases each containing a portion of light ends produced in the reaction, recycling a portion of the organic phase as reflux to the purge recovery zone and discarding the remainder. The entire aqueous phase of the overhead condensate of the purge recovery zone is discarded. The discarding of a portion of the organic phase and the entire aqueous phase of the overhead condensate of the purge recovery zone has the effect of preventing or retarding the buildup of ligth ends in the system.</p> |
