发明名称 A METHOD FOR SOLVENT FREE HYDRODEBROMINATION IN THE PRODUCTION OF AROMATIC CARBOXYLIC ACIDS
摘要 <p>A process for hydrodebromination of a molten crude product aromatic carboxylic acid prepared by liquid phase oxidation utilizing bromine as a component of the oxidation catalyst which comprises: recovering the crude product aromatic carboxylic acid mixture by distillation; extracting the crude product aromatic carboxylic acid mixture with water; and passing the aromatic carboxylic acid mixture over a catalyst selected from Group VIII of the Periodic Table, optionally on a support, at a temperature of from about 150-320 °C and a hydrogen partial pressure of from about 20 to 300 psig, thereby producing aromatic monocarboxylic acids having bromine compounds significantly reduced.</p>
申请公布号 WO2001016076(A1) 申请公布日期 2001.03.08
申请号 US2000023016 申请日期 2000.08.22
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