发明名称 SILANES INCLUDING ETHYNYL GROUP AND PRODUCTION THEREOF
摘要 PROBLEM TO BE SOLVED: To obtain a new silane compound containing a plurality of ethynyl groups on molecular chain ends having high hydrosilylating reactivity, capable of imparting an insoluble tough silicone based polymer material by carrying out a crosslinking reaction with a polymer material or the like having a plurality of Si-H bonds in a molecule. SOLUTION: This compound is expressed by the formula [A is a (substituted) para, mata, orthophenylene; R1 and R2 are each H, an alkyl or the like; n is 1-10], having two or more ethynyl groups on the ends of the molecular chain. The compound of the formula is obtained by reacting (A) a halogenosilane (e.g. phenhyldichlorosilane or the like) expressed by the formula: R1R2SiX2 (X is Cl, Br or I) with (B) an ethynyl metal compound obtained by reacting (i) a compound (e.g. m-diethynylbenzene or the like) expressed by the formula: HC≡C-A-C≡CH) with (ii) preferably, 1.0-1.5 mole times of an organic metal compound of the formula: RM (R is methyl, ethyl or the like; M is Li, Na or the like).
申请公布号 JP2001055393(A) 申请公布日期 2001.02.27
申请号 JP19990231970 申请日期 1999.08.18
申请人 SHIN ETSU CHEM CO LTD 发明人 TABEI EIICHI;MORI SHIGERU
分类号 C07F7/08;C08G77/60;(IPC1-7):C07F7/08 主分类号 C07F7/08
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