发明名称 HYDROGENATING CATALYST AND PRODUCTION OF ALCOHOLS FROM CARBOXYLIC ACIDS USING THE SAME
摘要 PROBLEM TO BE SOLVED: To obtain a catalyst capable of producing alcohols from carboxylic acids with high activity and high selectivity by using a catalyst containing a metal selected from the group consisting of ruthenium, platinum and rhodium, a metal selected from the group consisting of cobalt, nickel, manganese and iron and rhenium. SOLUTION: At least one kind of a metal selected from the group consisting of ruthenium, platinum and rhodium, at least one kind of a metal selected from the group consisting of cobalt, nickel, manganese and iron and rhenium are added to compose a hydrogenating catalyst. Carboxylic acids are hydrogenated in a liquid phase in the presence of the catalyst to produce alcohols in a high yield. At this time, the atomic ratio of platinum to rhenium is set to 0.1-5 and the atomic ratio of cobalt to rhenium is set to 0.1-10. The catalyst is supported on a carrier to be used and, as the carrier, an inorg. porous substance, activated carbon or graphite having a large surface area is used.
申请公布号 JP2001046874(A) 申请公布日期 2001.02.20
申请号 JP19990230362 申请日期 1999.08.17
申请人 MITSUBISHI CHEMICALS CORP 发明人 HARA YOSHINORI;KUSAKA HARUHIKO
分类号 B01J23/89;B01J23/656;C07B61/00;C07C29/149;C07C29/157;C07C31/20 主分类号 B01J23/89
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