发明名称 |
HETEROGENEOUS CATALYST FOR THE PRODUCTION OF ETHYLIDENE DIACETATE FROM DIMETHYL ETHER |
摘要 |
<p>This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.</p> |
申请公布号 |
CA2205316(C) |
申请公布日期 |
2001.02.06 |
申请号 |
CA19972205316 |
申请日期 |
1997.05.14 |
申请人 |
AIR PRODUCTS AND CHEMICALS, INC. |
发明人 |
RAMPRASAD, DORAI;WALLER, FRANCIS JOSEPH |
分类号 |
C07C67/293;(IPC1-7):C07C69/16;B01J31/06;C07C67/36;B01J31/16 |
主分类号 |
C07C67/293 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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