发明名称 TETRAHYDRONAPHTHALENE DERIVATIVE
摘要 PROBLEM TO BE SOLVED: To obtain a new tetralin which can largely lower threshold voltage without deteriorating responsibility and is useful for liquid crystal displays. SOLUTION: A compound of formula I [R is a 1 to 20C alkyl, an alkoxy, an alkoxyalkyl, an alkenyl or the like; (a) is 0 or 1; the ring A and the ring B are each trans-1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, pyridine-2,5-diyl or the like; L, M are each CH2CH2, CH=CH, CH2O, COO or the like; X1 to X3 are each H or F; Z is H, F, Cl, a (substituted) 1 to 20C alkyl or the like]. For example, 2-[2-(trans-4-propylcyclohexyl)ethyl]-6- fluoro-1,2,3-tetrahydronaphthalene. The compound of formula I is obtained, for example, by reacting a compound of formula II with a compound of formula III in the presence of Pd/C in a hydrogen pressure.
申请公布号 JP2001010991(A) 申请公布日期 2001.01.16
申请号 JP19990184786 申请日期 1999.06.30
申请人 DAINIPPON INK & CHEM INC 发明人 TAKEHARA SADAO;NEGISHI MAKOTO;NAGASHIMA YUTAKA;TAKATSU HARUYOSHI;GERHARD F GRAE;FRINGS RAINER BRUNO;PITHART CORNELIA DR
分类号 C07C13/48;C07C23/18;C07C25/22;C07C41/01;C07C43/184;C07C43/188;C07C43/192;C07C43/20;C07C43/205;C07C43/21;C07C43/215;C07C43/225;C07C69/75;C07C69/753;C07C69/76;C07C69/773;C07C69/78;C07C69/90;C07C255/52;C07C255/54;C07C255/57;C09K19/32;(IPC1-7):C07C13/48 主分类号 C07C13/48
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