发明名称 Catalyst for dehydrogenating amino alcohols to aminocarboxylic acids or ethylene glycol (derivatives) to oxycarboxylic acids, process for its preparation and application thereof
摘要 PCT No. PCT/EP97/05224 Sec. 371 Date Mar. 26, 1999 Sec. 102(e) Date Mar. 26, 1999 PCT Filed Sep. 24, 1997 PCT Pub. No. WO98/13140 PCT Pub. Date Apr. 2, 1998Catalyst for dehydrogenating amino alcohols to aminocarboxylic acids or ethylene glycol (derivatives) to oxycarboxylic acids, said catalyst containing zirconium, copper and possibly an additional metal, whereby the cited metals are precipitated as hydroxides, washed, dried, calcined, and reduced, preparable in that zirconium hydroxide is precipitated from an aqueous zirconium salt solution using a base until a pH of 4 to 10 is attained, the aqueous solution of a copper salt and possibly of an additional salt is added to the zirconium hydroxide suspension, and by adding further base copper hydroxide and possibly the hydroxide of the metal contained in the additional salt is precipitated until a pH of 8 to 14 is attained, the suspension obtained is filtered, washed, dried, calcined in air at 450 to 600 DEG C. for 2 to 4 hours and finally reduced at 200 to 250 DEG C. in a hydrogen stream for 2 to 4 hours.
申请公布号 US6159894(A) 申请公布日期 2000.12.12
申请号 US19990242560 申请日期 1999.03.26
申请人 AKZO NOBEL NV 发明人 EISENHUTH, LUDWIG;BERGFELD, MANFRED F.
分类号 B01J23/72;B01J37/02;C07B61/00;C07C51/16;C07C51/295;C07C59/125;C07C59/305;C07C227/02;C07C229/12;C07C229/16;C07C229/42;(IPC1-7):B01J23/00 主分类号 B01J23/72
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