发明名称 DENDRON AND FLUORESCENT EUROPIUM COMPLEX USING THE SAME AS LIGAND
摘要 PROBLEM TO BE SOLVED: To obtain a new compound capable of remarkably increasing the fluorescent ability of a europium complex (Eu3+) and suppressing the concentration extinction and thereby useful as a fluorescent labeling agent, etc., by providing a focal point part with a specific branched structure. SOLUTION: This dendron has a 2,4-substituted benzoic acid residue represented by the formula (R1 and R2 are each a dendrimer having an aromatic ring in a recurring unit) in a focal point. The recurring unit is preferably 5- dioxybenzyl group. The method for producing the dendron comprises initially carrying out etherifying reaction of benzyl halides (e.g. methyl 2,4- hydroxybenzoate) in the presence of a base (e.g. an alkali metal carbonate), then hydrolyzing the ester group in the focal point and finally acidifying the liquidity with hydrochloric acid, etc.
申请公布号 JP2000344712(A) 申请公布日期 2000.12.12
申请号 JP19990153493 申请日期 1999.06.01
申请人 MITSUBISHI CHEMICALS CORP 发明人 MOTODA KANEICHIRO;KAWA MANABU
分类号 C09K11/06;C07C65/24;C07F5/00;C08G65/00;(IPC1-7):C07C65/24 主分类号 C09K11/06
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