发明名称 |
Process for the preparation of octa-2,7-dienyl-1-amine from butadiene and ammonia in the presence of palladium complex catalyst |
摘要 |
Process for the preparation of octa-2,7-dienyl-1-amine by telomerization of butadiene with ammonia in a two-phase system in the presence of hydrophilic palladium complexes, characterized in that octa-2,7-dienyl-1-amine and octa-1,7-dienyl-3-amine are isolated separately from one another from the reaction mixture present after telomerization, and the octa-1,7-dienyl-3-amine isolated in this way is subjected to an isomerization reaction to form octa-2,7-dienyl-1-amine, and also novel triphenylphosphine mono- and dimethoxytri(sodium sulphonates) and the use of triphenylphosphine trimethoxytri(sodium sulphonates), triphenylphosphine trimethyltri(sodium sulphonates) and triphenylphosphine trifluorodi- and tri(sodium sulphonates) as ligands for the preparation of palladium complexes.
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申请公布号 |
US6147238(A) |
申请公布日期 |
2000.11.14 |
申请号 |
US20000512532 |
申请日期 |
2000.02.24 |
申请人 |
BAYER AKTIENGESELLSCHAFT |
发明人 |
TRAENCKNER, HANS-JOACHIM;JENTSCH, JOERG-DIETRICH;PRINZ, THOMAS;DRIESSEN-HOELSCHER, BIRGIT;KEIM, WILHELM |
分类号 |
B01J31/24;C07B61/00;C07C209/54;C07C209/60;C07C211/21;C07F5/02;C07F9/50;C07F15/00;(IPC1-7):C07F9/02;C07C209/04 |
主分类号 |
B01J31/24 |
代理机构 |
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代理人 |
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