发明名称 Thermoplastic molding materials based on an optionally rubber-modified vinylaromatic polymer comprise an antistatic polyether and a phenolic antioxidant for improved color stability
摘要 Thermoplastic molding materials based on an optionally rubber-modified vinylaromatic polymer comprise an antistatic polyether and a phenolic antioxidant selected from octadecyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate and 2,4-dimethyl-6-(1-methylpentadecyl)phenol. Thermoplastic molding materials comprise: (A) 95-99.9 parts by weight (pbw) of an optionally rubber-modified vinylaromatic polymer comprising: (a) 0-100 wt.% of a graft copolymer consisting of 10-95 wt.% rubber and 5-90 wt.% of grafted styrene, alpha -methylstyrene, ring-substituted styrene, methyl methacrylate, (meth)acrylonitrile, maleic anhydride and N-substituted maleimide, where the rubber has a glass transition temperature below 10 deg C and in the form of at least partially crosslinked particles with a mean diameter of 0.05-20 mu m; and (b) 0-100 wt.% of a thermoplastic polymer of styrene, alpha -methylstyrene, ring-substituted styrene, methyl methacrylate, (meth)acrylonitrile, maleic anhydride and N-substituted maleimide; and (B) 0.1-5 pbw of a mixture of: (c) a polyalkylene ether, optionally modified with radical formers or acid groups, with a number-average molecular weight of 500-20,000; and (d) a phenolic antioxidant selected from octadecyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate and 2,4-dimethyl-6-(1-methylpentadecyl)phenol; where the (c):(d) weight ratio is 1-20:1.
申请公布号 DE19917568(A1) 申请公布日期 2000.10.26
申请号 DE19991017568 申请日期 1999.04.19
申请人 BAYER AG 发明人 WILLENBERG, BERND;EICHENAUER, HERBERT;ALBERTS, HEINRICH
分类号 C08L25/00;C08K5/13;C08K5/17;C08K5/375;C08L25/16;C08L51/04;C08L71/02;(IPC1-7):C08L51/04;C08L25/08;C08K5/134;C08J3/20 主分类号 C08L25/00
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