发明名称 PRODUCTION OF 2,6-NAPHTHALENEDICARBOXYLIC ACID
摘要 PROBLEM TO BE SOLVED: To provide a method for producing highly pure 2,6- naphthalenedicarboxylic hardly containing a ring-brominated naphthalenedicarboxylic acid which is an impurity, without using an expensive solvent and without requiring equipment corresponding to a high temperature and high pressure condition. SOLUTION: An aqueous solution of a crude dialkali salt of 2,6- naphthalenedicarboxylic acid is subjected to a reduction treatment in the presence of zinc, and the treated aqueous solution is acidified to precipitate a highly pure crystal. Further, when the aqueous solution of the dialkali salt of the 2,6-naphthalenedicarboxylic acid after the reduction treatment is treated with an absorbent, the purer crystal can be obtained. The crude dialkali salt of the 2,6-naphthalenedicarboxylic acid is preferably the one obtained by adding the crude 2,6-naphthalenedicarboxylic acid to an aqueous solution obtained by dissolving one or more selected from a group of sodium hydroxide, sodium carbonate, potassium hydroxide, potassium carbonate and ammonia in an amount of the neutralizing equivalent or more.
申请公布号 JP2000297059(A) 申请公布日期 2000.10.24
申请号 JP19990107078 申请日期 1999.04.14
申请人 KOBE STEEL LTD 发明人 YOSHIKAWA EIICHIRO;HAMAGUCHI MAKI
分类号 C07C51/02;C07C51/47;C07C51/48;C07C63/38;(IPC1-7):C07C51/02 主分类号 C07C51/02
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