Silicoacrylic compositions, preparation process and use for obtaining coatings which are hardenable thermally or by radiation

摘要

Silicoacrylic compositions which are fluid, polymerizable thermally or by radiation, by a radicular mechanism, with a very low water (less than 1.5%) and volatile solvent content containing silica, a silane and a multifunctional acrylic monomer, in which the silica is in the form of individualized particles, with an average diameter comprised between 5 and 100 nm, not linked together with siloxane bonds, the silane is a vinylsilane of formula (1) H2C=CH-Si(OR)3(I)in which R represents a methyl or ethyl radical, in which the multifunctional acrylic monomer is tripropylene glycol diacrylate designated TPGDA, the quantity of vinylsilane of formula I is comprised between 0.01 millimole and 0.1 millimole per m2 of silica used and which are transparent and colourless as water and stable over time and preparation process.