发明名称 |
Process for selective oxidation of primary alcohols and novel carbohydrate aldehydes |
摘要 |
A process for producing nitrosonium ions is described, in which a nitroxyl compound such as TEMPO is oxidized using an oxidizing agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine. The process is useful for the oxidation of carbohydrates containing at least 1 cyclic monosaccharide chain group carrying a carbaldehyde group per 100 or per 25 monosaccharide units and per molecule. |
申请公布号 |
AU2832800(A) |
申请公布日期 |
2000.09.14 |
申请号 |
AU20000028328 |
申请日期 |
2000.02.24 |
申请人 |
NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJ K |
发明人 |
JAN MATTHIJS JETTEN;RONALD TAKO MARINUS VAN DEN DOOL;WIM VAN HARTINGSVELDT;MARIO TARCISIUS RAGMANDUS VAN WANDELEN |
分类号 |
C12P17/12;C07C45/29;C07C45/32;C07C45/38;C07C45/39;C07C239/08;C07H1/00;C07H3/00;C07H5/04;C07H7/033;C08B1/00;C08B31/18;C08L1/00;C08L3/00;C12P1/00;C12P7/24;C12P13/00;C12P19/00;C12P19/04;C12P33/00;C12S11/00 |
主分类号 |
C12P17/12 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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