发明名称 PRODUCTION OF AMINOCARBAZOLES
摘要 PROBLEM TO BE SOLVED: To provide a method, which can stably produce an aminocarbazole in high yield while preventing deteriorated reaction rate, yield or the like by lot of the nitrocarbazole as the stock. SOLUTION: This method is to produce an aminocarbazole by catalytic reduction of the nitrocarbazole, wherein the catalyst is a nickel-based catalyst, activated with an alkali and iron compound in an inert solvent in a hydrogen or inert gas atmosphere. It is preferable that the activated nickel-based catalyst contains the iron compound at 10 to 60 wt.% as the metal, based on the nickel- based catalyst, and that the nitrocarbazole is 1-nitro-9-lower alkyl substituted carbazole and/or 3-nitro-9-lower alkyl substituted carbazole.
申请公布号 JP2000229943(A) 申请公布日期 2000.08.22
申请号 JP19990000430 申请日期 1999.01.05
申请人 SUMITOMO CHEM CO LTD 发明人 KAMIKAWA TAKU;MARUYAMA OSAMU
分类号 B01J25/02;C07B61/00;C07D209/88;(IPC1-7):C07D209/88 主分类号 B01J25/02
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