发明名称 CURABLE COMPOSITION AND DENTAL RESTORATION MATERIAL COMPRISING THE SAME
摘要 PROBLEM TO BE SOLVED: To obtain a curable composition excellent in clarity, hardness, and abrasion resistance by incorporating a silica-base polycondensate obtained by the hydrolysis and polycondensation of a methacryloyloxysilane compound and a phenylsilane compound, a polyfunctional (meth)acrylate, and a polymeriza tion initiator into the same. SOLUTION: A phenylsilane compound (e.g. phenylmethoxysilane) represented by formula II is subjected to hydrolysis and polycondensation in the presence of a compound which is obtained by subjecting a methacryloyloxysilane compound represented by formula I to hydrolysis and polycondensation in the presence of colloidal silica having an average particle size of 1-100 nm, thus giving a silica-base polycondensate (A). Then, 100 pts.wt. mixture comprising 5-95 wt.% ingredient A and 95-5 wt.% polyfunctional (meth)acrylate (B) represented by formula II is compounded with 0.01-10 pts.wt. polymerization initiator and 10-500 pts.wt. filler (e.g. a silica powder), giving a curable composition. In the formulas, R1 and R6 are each H or methyl; R2 and R4 are each a 1-3C alkyl or the like: R3 and R5 are each H or a 1-10C hydrocarbon group; (p) and (r) are each 0-2; (q) is 1-6; and (m) and (n) are each 1-5.
申请公布号 JP2000226488(A) 申请公布日期 2000.08.15
申请号 JP19990027175 申请日期 1999.02.04
申请人 MITSUBISHI RAYON CO LTD 发明人 ISHITA HITOSHI;WATANABE YUKIO;YANAGASE AKIRA
分类号 A61C13/087;A61K6/083;C08L33/14;(IPC1-7):C08L33/14 主分类号 A61C13/087
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