发明名称 METHOD OF PREPARING SOLID TITANIUM CATALYTIC COMPONENT, OLEFIN- POLYMERIZATION CATALYST CONTAINING THEREOF, AND OLEFIN POLYMERIZATION PROCESS
摘要 polymerization catalysts and processes. SUBSTANCE: catalytic component contains magnesium, titanium, halogen, and electron-donor compound, does not lose titanium on washing with hexane at room temperature and loses less than 15 wt.% of titanium on washing with o-dichlorobenzene at 90 C. Catalytic component can be prepared by a method wherein non-removable in contact with hexane titanium is brought into contact with polar compound (dipole moment 0.50 to 4.00 Debye) causing at least 25 wt.% decrease in titanium content to give catalytic component with weight ratio of electron-donor compound to titanium is at least 7:1. Olefin-polymerization catalyst containing this component can be used in (co)polymerization of olefins and is distinguished by high activity relative to formation of high- stereoregularity polyolefin while low-stereoregularity polyolefins are formed in reduced amounts. EFFECT: increased specific selectivity of catalyst. 8 cl, 1 dwg, 5 tbl, 26 ex
申请公布号 RU2153932(C2) 申请公布日期 2000.08.10
申请号 RU19960110072 申请日期 1996.05.16
申请人 MITSUI KEMIKALS, INK. 发明人 KOZHOKH SHINICHI;KIOKA MAMORU
分类号 B01J31/38;B01J37/00;C08F4/646;C08F4/654;C08F4/656;C08F10/00;(IPC1-7):B01J31/38 主分类号 B01J31/38
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